论文标题:Directly converting CO2 into a gasoline fuel
期刊:Nature Communications
作者:Jian Wei, Qingjie Ge, Ruwei Yao, Zhiyong Wen, Chuanyan Fang, Lisheng Guo, Hengyong Xu & Jian Sun
发表时间:2017/05/02
数字识别码:10.1038/ncomms15174
原文链接:https://www.nature.com/articles/ncomms15174?utm_source=Other_website&utm_medium=Website_links&utm_content=RenLi-Nature-Nature_Comms-Catalysis-China&utm_campaign=NATCOMMS_USG_JRCN_RL_sciencenet_convertingCO2_Aug_2nd
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《自然-通讯》发表了一篇题为“Directly converting CO2 into a gasoline fuel”的研究论文,在文章中,中国科学院大连化学物理研究所的Jian Sun和Qingjie Ge所带领的研究团队展示了一项最新的研究成果,即通过一种全新的Na-Fe3O4/HZSM-5多功能复合催化剂,首次实现了通过将CO2直接加氢制取高辛烷值汽油。
这种直接以CO2作为原料生产液态燃料的方法,引起了人们的极大关注,因为其不仅可缓解CO2排放,同时还可减轻对化石能源的依赖,可谓一举两得。研究者指出,通过一种高效稳定的Na-Fe3O4/HZSM-5多功能复合催化剂,可以直接将CO2转化为汽油范围(C5-C11)内的烃类化合物,其选择性高达所有烃类的78%,而在工业相关条件下,CO2转化率为22%时甲烷只占4%。该多功能催化剂包含三种协同催化的活性位点(Fe3O4、Fe5C2和酸性位点),可以共同催化一系列串联反应。此外,对三种活性位点的结构及其亲密性效应的调控是实现CO2加氢制备汽油的关键。同时该多功能催化剂具有良好的稳定性,可持续作用1000 h以上,未来有望将其作为工业催化剂,用于实现CO2加氢制取液态烃燃料。
摘要:The direct production of liquid fuels from CO2 hydrogenation has attracted enormous interest for its significant roles in mitigating CO2emissions and reducing dependence on petrochemicals. Here we report a highly efficient, stable and multifunctional Na–Fe3O4/HZSM-5 catalyst, which can directly convert CO2 to gasoline-range (C5–C11) hydrocarbons with selectivity up to 78% of all hydrocarbons while only 4% methane at a CO2 conversion of 22% under industrial relevant conditions. It is achieved by a multifunctional catalyst providing three types of active sites (Fe3O4, Fe5C2 and acid sites), which cooperatively catalyse a tandem reaction. More significantly, the appropriate proximity of three types of active sites plays a crucial role in the successive and synergetic catalytic conversion of CO2 to gasoline. The multifunctional catalyst, exhibiting a remarkable stability for 1,000 h on stream, definitely has the potential to be a promising industrial catalyst for CO2 utilization to liquid fuels.
阅读论文全文请访问:https://www.nature.com/articles/ncomms15174?utm_source=Other_website&utm_medium=Website_links&utm_content=RenLi-Nature-Nature_Comms-Catalysis-China&utm_campaign=NATCOMMS_USG_JRCN_RL_sciencenet_convertingCO2_Aug_2nd
(来源:科学网)
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