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标题：Temperature-Controlled Catalytic Growth of ZnS Nanostructures by the Evaporation of ZnS Nanopowders
来源：《先进功能材料》2005年15卷第1期，63-68页
作者：中科院固体物理研究所 Xiao-Sheng Fang（方晓生）, Chang-Hui Ye（叶长辉）, Li-De Zhang（张立德）, Yin-Hai Wang（王银海）, Yu-Cheng Wu（吴玉程）
Research Fronts: TEMPERATURE-CONTROLLED CATALYTIC GROWTH; TEMPERATURE-CONTROLLED GROWTH; GROWTH PROCESS; TWINNING-MEDIATED GROWTH; AL2O3 NANOBELTS
领域：材料科学
摘要：ZnS nanostructures with different morphologies, sizes, and microstructures were synthesized by the evaporation of ZnS nanopowders. Based on the appearance of the as-synthesized products, we show that substrate temperature and catalyst are the critical factors for controlling the size and the structure of various kinds of ZnS nanostructures, such as nanorods, nanowires, nanobelts, and nanosheets. Within a certain temperature range, products with a specific morphology can be obtained. Therefore, it may be possible to obtain ZnS nanostructures with a specific morphology by controlling the reaction temperature and catalyst. This represents an important step toward the design and control of nanostructures. High-resolution electron microscopy revealed that most of the nanorods and nanowires grew along the [100] direction, whereas most of the nanobelts and nanosheets grew along [001]. Photoluminescence properties and growth mechanisms of these as-synthesized ZnS nanostructures are discussed.
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